Dancing on Surfaces:
Self-Assembly of Particles and Bubbles
John L. Anderson, PhD
Provost
and University Vice President
Professor of Chemical Engineering
Case Western Reserve University
Date: Thursday,
January 27, 2005
Time: 3:30 pm
Location: Mary Gladwin Hall,
Room 111
Additional Information: Contact: Dr. S. I. Hariharan,
330.972.6580 |
In
the process of electrophoretic deposition (EPD), coatings are
formed by forcing particles in solution toward an electrode with
an electric field. After the particles reach the electrode surface,
they move laterally to either aggregate into clusters or separate,
depending on solution conditions and the frequency of the field.
With dc electric fields the particles move together to form doublets
and triplets, and then higher order clusters until a dense monolayer
film is produced as more particles deposit. When the direction
of the field is reversed for a partial monolayer, the particles
separate. Experimental data verify that electroosmotic flow about
each particle on the electrode entrains its neighbors, and a
theory has been developed for two and three particle interactions.
A similar phenomenon occurs with bubbles near surfaces. Two bubbles
come together on a hot surface but move apart on a cold surface.
Again, convection caused by a Marangoni flow about each bubble
causes the motion. A theory based on this flow is able to predict
the motion of the bubble pairs.
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